How big of a tank and where does the brittle star "hang out". If it is in a convient place to catch him, just use a piece of krill or seafood big enough to hold between your fingers. If you can reach the brittle star with this bait, it will be hard for him to resist going after it and he will likely wrap around your fingers to get the bait. Then you can kind of gently move him out away from the rock and just pull him out. I finger feed mine a lot, especially when i want to freak out company!
Arrow crabs also eat asterina stars but can be damaging to other stuff as well.