OK, post #5 is a little harsh IMO. Personally I applaud you for thinking outside the box and doing the research. Too many folks jump in this hobby and then ask questions to fix the problems that could have been avoided if they had just asked first.
So, with regards to sunlight. I have actually researched this a fair bit as I mentioned above and it has been done with both the sola-tubes and skylights. The main issues as I see it are two fold.
First, the color. Natural sunlight has plenty of light in all spectra's, but as noted above is most visibly around 6500K. I've actually grown corals under 6500K bulbs and it's great for growth, but things tend to look more brown/green. The normal 10000K and higher bulbs used for reef aquaria are much more blue and coupled with the actinic commonly used as well make many of the colors in our tanks "pop". Additionally lower K temps tend to grow algae better. I don't know if a well run tank would have more algae problems with natural sunlight or not. It seems to me if setup properly limiting nutrients would keep algal growth at bay just as it does with higher K lighting.
Second, are seasonal issues with intensity and photo-period. As someone else mentioned sunlight in the tropics is pretty constant all year round. To that end, and to some degree issue #1 as well, dictates that some supplemental lighting would need to be employed.
Now for the fun part. Some pics of tanks that use natural sunlight!
First up several variations using Sola-tubes:
BTW...Sola-tube says there 21" diameter skylight emits the same amount of light as a 250W MH:
and this is the guy who installed a 4'x8' skylight above his tank:
I'm not sure of the depth of the tank, but I think a PAR reading like that in the lower regions of a 700 gallon tank is pretty good:
So, in conclusion, can it/has it been done? Definitely. Is it easy or cheap? Probably not cheaper in the short term, but the savings in electrical cost over time is probably somewhat sizable. Easier? I think it takes a good deal of careful planning and I do have to agree with Sir Deut III that it is probably not a project you want to engage in for your first foray into reef keeping.
Welcome again, and good luck!