Hrm... don't you hate it when the animal doesn't know the drill...

I wouldn't leave the live rock in the freshwater too long, since it may harm the beneficial bacteria in it (not sure, but it sounds logical).
Some people have luck using seltzer water also (like club soda) since the carbonation flushes them out pretty fast (they aren't very fond of CO2). Just put the rock in an empty bowl and apply it with a turkey baster or syringe aimed in the hole it's hiding in.
Otherwise, I don't know what else you could try... somebody else might have a suggestion.