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Search google for "peltier module," "TEC" or "thermoelectric module," you will find tons of info on how these work.
They are a heat pump, they move heat energy from one sid of the module to the other. Keep in mind that they can only move as much heat as they can dissapate i.e. a 200+ watt module will need a very efficient or very large heat sink.
They also consume a LOT of energy, that specific one will use up to 20 amps at 12 volt DC, so you need a large expensive power supply to control it.
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~Vince
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