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Well hello and welcome to the hobby... you'll find it a lot of fun! As far as the live sand questions... which comes first, the sand or the rock ... that is a good question! Hopefully someone else on here will be able to answer that one for you.
As far as the 5 Ga being a beginner tank... heck yeah! the smaller the tank, the more volitile it will be, so extra care is required and frequent checks and balances. It trains you up good for when you will go to a larger tank.
Good luck with your endeavor! using water from the LFS's tank and LR from there also... very little cycling will be required. The rock is already established with the water... so it should be ready to add a cleaning crew to immediately.
Just don't make the mistake of overstocking the tank. This kind of tank requires a great deal of reservation and research when deciding on new species to introduce. Enjoy the corals, they will flourish under the right lighting and water circulation... but don't plan on more than one or two SMALL fish.
Best wishes! show us pictures when you're all set-up!
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