Two issues with it:
It's glass .... weight is a big issue. As would be worry over breaking ... and you do know that the backing that makes the glass a mirror will degrade over time.
Loss of light. The reflector in a mirror is really at the very back of the glass ... so the light is going thru the glass twice on reflector = loss of intensity. A polished aluminum reflector has no 1/4" or so of glass to go thru.
Maybe not a huge issue ... but given mirrors are flat [not the most efficient reflector design] and you lose intensity by running light through the glass twice .... then the other worries start to weigh things down IMO.
I'd check out
www.advancedaquarist.com - March 2003 and some other archived articles by
Sanjay Joshi on reflectors. I believe his work suggested a good reflector will give 20-30% more light than using something else.
My 2 cents.