I have been using
Krylon Fusion to paint my new overflows and sump baffles (so the silicone will stick) and have had really nice results. I was getting ready to glue the first overflow in, so I put on a final coat on my second overflow. I walked into the garage today at lunch and I checked on my second overflow (I was hoping to glue it in while I was there), I saw that the paint was crackled and looked like it was going to peel right off. I grabbed a corner and started to pull and basically pulled the whole finish right off.

I ended up using a new razor blade and just scraped everything else off (it wasn't difficult whatsoever).
I took it inside and scrubbed it real well with White Vinegar hoping it was just a fluke. Before I left I put on a real thin coat of Krylon, so we'll see how it turns out when I get home.
Has anyone had this sort of problem? Does acrylic have a side that won't let paint stick?