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It looks to me as if your UV Sterilizer isn't allowing enough flow through it. the first sump is always the same because the same flow from the tank is always overflowing into the first sump. Because there is a set volume of flow though the sterilizer, the same amount is always in the 1st sump. When water evaporates, the same flow is maintained through the sterilizer, and to the tank, so the water goes down in the 2nd sump. If you ran larger lines to the sterilizer or made the line more curved instead of elbows, it would probably flow faster, and both sumps would be closer to even. The first would have less water, and the 2nd would have more water. You may be at the limit of flow on your system. If you got a larger pump, you might just empty your second sump while the first was still trying to drain into it.
I hope that makes sense. That's what I think it sounds like.
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125G AGA, dual overflows, 190 lbs live rock, 120 lbs crushed coral, ETSS 800 skimmer, 6' Pro Clear Aquatics w/3 150W 10k XM HQI MH, 72w actinic, 100G stock tank sump. Crocea Clam, 2 Clarkii Clowns, Hippo Tang, Yellow Tang, 5 Pajama Cardinals, 1 cleaner shrimp, 1 blood shrimp.
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