Low pH: Tap water? If so, what worked for me: the Reef buffer 8.3, if not helps - check the
Magnesium levels. IO salt, by any chance? This is what I'm using.
Nitrates: causes and cures
Cures: water changes and refugium. Causes - to prevent build up of NO3, try to remove all unused food and the visible wastes, improve filtration or
protein skimming. Can give links, depending on what you are using, if you will be interested.
There should be an article online, Randy Holmes-Farley, Low pH - causes and cures, if I remember right. The different version of correcting pH. He is the leading specialist in water chemistry.