Seems at that time of day your pH is a little low. AT that time of day you should be somewhere around the peak for pH. 8.0 is a figure you would most likely get at the low pH time, somewhere just before your main lights start to come on. Double check that test with someone elses test kit if possible and fix if a problem really does exist. When comparing pH tests make sure you do the tests at the same time of the day or the test isn't really a valid comparison.
If I'm understanding the calcium question correctly --- I do not beleive you could really get a calc of 1,000. Long before that the calcium would be falling out of solution and forming as a white dusting all over everything. Need to retest for calcium using somebody elses kit or at least new reagents. Also double check your reading and math just to make sure you didn't do anything "HOMER" like.
Alk reading seems fine (could be a little higher but OK just the same)
My conclusion (just from what info you gave):
Calcium test is wrong. Problem is probably more w/ your pH being a little low.
All this was JMO and maybe gives you somewhere to start looking --- Charles