First, with regards to PH, artificial salt water mixes are PH buffered, so adding unbuffered RO/DI or tap water as topoff water will not have a significant effect on PH.
Second, using de-chlorinated tap water is a disaster waiting to happen. There is just too much variability in local water supplies. Not only do water agencies add chlorine and chloramine to the water which you would have to buy de-chlorinators to remove, but they also allow and even add high levels of phosphates and disolved organics which will full
algae blooms. On top of all that, they often change their recipe of additives on a seasonal basis, so you may going along ok for a couple months, then all of a sudden you get a massive
algae bloom or tank crash because of some new additive.
With RO/DI, you are taking out all the variables. You are giving your tank the purest water possible to start with, without having to worry about unintentionally adding something dangerous. On top of that, I gaurantee that any additions of kalkwater or baking soda you might add to buffer PH or alkalinity will be cheaper than the de-chlorinator you would have to add to treat your tap water.
When I first started in the hobby, I thought I could get by with tap water. When that failed me, I thought the RO water from vending machines would be good enough, but it wasn't. Now that I have my own RO/DI system, I could never in good conscience recommend anything less. The $200 I spent has not only made reefkeeping so much easier for me, but also supplied my family with great quailty drinking water. It's a win-win situation all the way around.