bigjohn,
Were the PH and
ORP probe tips kept in storage solution? If not, they will need to be replaced, they cannot be allowed to dry out.
If they were stored correctly, yes they can be calibrated. For the PH probe, you will need to get calibration solutions of 7 & 10. You can also get ORP
calibration solution. The manual has instruction for calibrating. Just remember that when it comes to ORP, it's best to use it to watch trends, either up or down and not to try to get to a particular value. ORP monitors are not very accurate but will tell you if water quality is going up or down.
As far as cleaning, Tom posted a great probe cleaning procedure a while back, try doing a search. HTH
Ron