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You can order dry base rock from marcorocks.com for a dollar a pound.
Issues with oysters? Aside from whats already been mentioned, when the oyster eventually dies, everything it has ever eaten will be released right back into the water column. If you remove them occassionally, you have the issue of having to replace them. Simply get some base rock, give it 6 months or so, it will be live rock.
And, you don't have to worry with the oysters. I wouldn't use the shells for substrate either. As close in as they live in the ocean to society, they are going to be phosphate loaded among other things, be hard to keep clean, just a lot of issues with using them for that (I have asked about using the shells for substrate before).
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