Quote:
Originally Posted by jersey jeff
...wondering how to control the swing of ph during night time. I just recently started adding kalkwasser with a five gallon dosing tank. Dkh is a little high about 14 calcium is 410 ph during the day 8.23. I'm afraid if I up the dose of kalk the salinity may drop
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You do not need more kalk, adding or increaing the alkainity in your tank will not control the swing you are experiencing. The swing in pH is controlled byhow much CO2 is present in the water, and as the pH is almost in constant equilibrium with the atmosphere (and buffer equilibrium is much slower), changes in water column pH are more directly a reflectiion of the pCO2 in the water (its equilibrium rate is much faster than rates of change induced by the bicarbonate/carbonate buffer system).
While the lights are on, photosynthesis rates by photoautotrophs (like coralline algae or
Zooanthellae are usually very rapid, and their rate of consumption of CO2 can easily exceed the rate at which CO2 can diffuse back into the tank water, so pH gradually rises up to peak pH levels of 8.3 to 8.5 by the end of the photoperiod. When the lights go out, photosynthesis stops using CO2, and even the photoautotrophs become net producers of CO2 as they turn stored CHO's into CO2 via cellular respiration for the chemical energy during the night. This causes the pH to fall during the night, usually to a nadir of 8.0 to 7.9 depending on several factors.
As already pointed out, there is no issue with the system's diurnal swing in these values, and unless you're introducing a new Ca reactor and the nadirs are below 7.9 at night, then you really do not have any issues in this situation.
Normal tank variation, nothing to worry about.
HTH