Call Hach, they sell PH calibration "powder pillows" for making calibration solution. You can go to thier website and do a search by "parameters" PH... Then click on "Buffers, pH standardization " ... It will show you all of the powders and liquids they have available for PH calibration. In order to see prices online you will have to "register" with them.
http://www.hach.com/
Product #2227064 7.0 PH calibration pillows 250 pieces $46.15
Product #2227066 7.0 PH calibration pillows 50 pieces $11.25
Product #2227164 10.0 PH calibration pillows 250 pieces $46.15
Product #2227166 10.0 PH calibration pillows 50 pieces $11.25
Product #2226964 4.01 PH calibration pillows 250 pieces $46.15
Product #2226966 4.01 PH calibration pillows 50 pieces $11.25
Product #2299264 Buffer, pH 4.01 & pH 7.00, 10 Powder Pillows of each $7.50
Product #2299277 pH Buffer, 4.01 and 7.00, pk/20 Powder Pillows (doesn't give price)
Product #1407995 Buffer, pH 8.00, pk/15 Powder Pillows $7.15