depending on the skimmer. the major detrital remover could be you.

this is prolly the most important part of doing water changes is removing piles of detritus.
using cannister filters for an hour after a water change or a major tank reaquascaping is fine, but running it longer just makes it a nutrient exporter. what happens is the trapped detritus decomoses releasing its bound nutrients back into the system because of the flow going through it. if it was a pile of detritus on the ground it would just sit there and the leaching back into the water column would be significantly less.
filter sponges are the biggest culprits for this.
G~